Molar Mass of Oxalic acid

The molar mass of oxalic acid (C2H2O4) is 90.034 g/mol, derived element by element, with composition by mass.

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The molar mass of oxalic acid, C2H2O4, is 90.034 g/mol. That single number is what connects a mass you can weigh to an amount of substance you can react: one mole is 90.034 g, and a gram of it is 6.689e+21 formula units. The calculator turns any weighed mass into that count, and reports the amount in moles, millimoles and the mass of a single formula unit alongside it.

The figure comes from the formula. Oxalic acid is 2 × 12.011 (C) + 2 × 1.008 (H) + 4 × 15.999 (O), which is 90.034 g/mol, taking standard atomic weights, and every page here computes that sum rather than quoting it. Oxygen makes up the largest share of the mass: 4 of the 8 atoms in a formula unit are oxygen, and they account for 63.996 g of the 90.034 g, or 71.08% by mass. The derivation table below breaks the whole molecule down element by element.

The numbers a bench actually uses sit at the millimole scale. One millimole of oxalic acid is 90.034 mg and one micromole is 90.034 µg, so a balance reading to a milligram places you within 11.11 µmol. A single formula unit weighs 1.4950e-22 g, which is why the count in the gauge runs into the sextillions for any mass you can see.

Rust remover, wood bleach and the acid in rhubarb leaves. The dihydrate is the form usually sold, at 126.07 g per mole, and it is genuinely toxic. At 90.034 g/mol it is heavier than 5 of the 12 acids covered here, and that ranking matters more than it looks: nitric acid has a molar mass of 63.012 g/mol, so a gram of it contains 42.9% more formula units than a gram of oxalic acid. Weigh by mass and you are not weighing equal amounts of substance.

One more step applies if you are starting from a concentrated bottle. Concentrated acids are labelled as a percentage by weight together with a density, not as a molarity, so getting to mol/L means multiplying density by that percentage and dividing by 90.034 g/mol. A page like this one gives you the last of those three numbers; the first two are on the bottle, and they vary between grades.

The formula

N = m ÷ 90.034 × 6.02214076×1023
m
The mass of oxalic acid in grams
90.034
The molar mass of oxalic acid in g/mol, derived from its formula
N
The number of formula units that mass contains

How it works, step by step

  1. Enter a mass of oxalic acid in grams.
  2. It is divided by the molar mass, 90.034 g/mol, giving the amount in moles.
  3. That amount is multiplied by the Avogadro constant, 6.02214076 × 10²³ per mole, to give the number of formula units.
  4. The panel also reports the amount in moles and millimoles and the mass of one formula unit.

Worked examples

0.5 g of oxalic acid as a molecule count

0.5 g divided by 90.034 g/mol is 0.00555346 mol, and multiplying by the Avogadro constant gives 3.344e+21 formula units of oxalic acid. The same mass is 5.5535 mmol, which is the figure a reaction is actually planned in.

5 g of oxalic acid as a molecule count

5 g divided by 90.034 g/mol is 0.0555346 mol, and multiplying by the Avogadro constant gives 3.344e+22 formula units of oxalic acid. The same mass is 55.535 mmol, which is the figure a reaction is actually planned in.

50 g of oxalic acid as a molecule count

50 g divided by 90.034 g/mol is 0.555346 mol, and multiplying by the Avogadro constant gives 3.344e+23 formula units of oxalic acid. The same mass is 555.35 mmol, which is the figure a reaction is actually planned in.

How to read your score

0–0NothingNo mass, no molecules.
0–—Milligram scaleUnder 6.689e+18 formula units — the amount in a milligram or less of oxalic acid. Still an enormous count, which is the point of the mole.
—–—Bench scaleThe range from a milligram to ten grams, where nearly all weighing of oxalic acid is done.
—–—Bulk scaleMore than ten grams. Beyond a few hundred grams the count is better handled in moles than in formula units.

Frequently asked questions

What is the molar mass of oxalic acid (C2H2O4)?

It is 90.034 g/mol. That is the sum of the standard atomic weights of every atom in the formula: 2 × 12.011 (C) + 2 × 1.008 (H) + 4 × 15.999 (O). One mole of oxalic acid therefore weighs 90.034 g, and a gram of it is 11.107 mmol.

What percentage of oxalic acid is oxygen?

71.08% by mass. Each formula unit contains 4 oxygen atoms contributing 63.996 g of the 90.034 g total, so 100 g of oxalic acid contains 71.08 g of oxygen and a kilogram contains 710.8 g of it.

How many molecules are in one gram of oxalic acid?

About 6.689e+21. One gram is 0.0111069 mol, and each mole contains 6.02214076 × 10²³ formula units by definition of the mole, so the count is that constant divided by 90.034.

How much does a single molecule of oxalic acid weigh?

1.4950e-22 g, which is 90.034 daltons. It is the molar mass divided by the Avogadro constant, and the number in daltons is numerically the same as the molar mass in g/mol — that equivalence is what makes the mole convenient.

Is molar mass the same as molecular weight?

They are the same number in ordinary use but not the same quantity. Molecular weight, properly relative molecular mass, is a ratio and has no unit: for oxalic acid it is 90.034. Molar mass carries grams per mole: 90.034 g/mol. Because the mole is defined so those agree, you can read one off the other.

Why is the molar mass not a whole number?

Because standard atomic weights are averages over the isotopes found in nature. Oxygen is quoted as 15.999 rather than a whole number for that reason, and the same applies to the other elements here, which is why oxalic acid comes out at 90.034 g/mol rather than 90.

Molar mass, composition and mole equivalents of oxalic acid

How the molar mass of oxalic acid is arrived at
ElementAtomsAtomic weightContribution (g/mol)By mass
Oxygen (O)415.99963.99671.08%
Carbon (C)212.01124.02226.68%
Hydrogen (H)21.0082.0162.239%
Total — one mole of oxalic acid90.034100%

Standard atomic weights, IUPAC 2021. The contribution column is atoms × atomic weight, and the total is the molar mass this page uses: 90.034 g/mol.

Mole quantities of oxalic acid and what they weigh
AmountMass (g)Mass (mg)Formula units
1 µmol0.0000900.0900346.022e+17
10 µmol0.000900340.900346.022e+18
100 µmol0.00900349.00346.022e+19
1 mmol0.09003490.0346.022e+20
10 mmol0.90034900.346.022e+21
50 mmol4.50174501.73.011e+22
100 mmol9.00349003.46.022e+22
250 mmol22.508522,508.51.506e+23
500 mmol45.01745,0173.011e+23
750 mmol67.525567,525.54.517e+23
1 mol90.03490,0346.022e+23
2 mol180.068180,0681.204e+24
5 mol450.17450,1703.011e+24
10 mol900.34900,3406.022e+24

Mass is the amount multiplied by 90.034 g/mol. The last column is that amount multiplied by the Avogadro constant, 6.02214076 × 10²³ per mole.

Oxalic acid among other acids, by molar mass
CompoundFormulaMolar mass (g/mol)Millimoles in 1 g
Acetic acidCH3COOH60.05216.652
Boric acidH3BO361.83116.173
Nitric acidHNO363.01215.87
Oxalic acid (this page)C2H2O490.03411.107
Lactic acidC3H6O390.07811.101
Phosphoric acidH3PO497.9937610.205
Sulfuric acidH2SO498.07210.197

Ordered by molar mass. The last column is 1000/M, which is the number a weighed gram actually gives you.

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